I got the blank cards and the printer but LibreWriter isn't very intuitive.
LibreOffice used to have templates for Avery's business card stationery.
I could not find any and I am assuming you tried it as well :(
Alternatively, you can go to
Avery's website (a
bit.ly URI), select the form type, create your biz card there, and download the PDF to print it on your printer.
I have done this for return address labels and it is awesome.
Caveat: When printing - in the printer dialog box select "no margins" or the equivalent, print a test page on a blank sheet, and visually check for alignment with your stationery. You have been warned :)
I also suggest that you include a QR code for your biz (the textual information) and put it in a corner of the card. That way people who don't want to carry paper cards can scan your biz details.
Hope this helps.